Maitiro Ekugadzira Nickel-Phosphorus Plating Asina Electroless

1. Chinangwa

Kugadzirisa maitiro ekuisa nickel plating isina electroless, kutonga kweparameter, uye zvinodiwa zvemhando, kuve nechokwadi chekuti coating yakagara yakasimba inosangana nezvinodiwa nevatengi uye zvepasi rose.

2. Chiyero

Inoshanda pakugadzira nickel isina magetsi pasimbi yekabhoni, simbi isingatsvi, uye alloys dzemhangura. Haishande kune alloys dzemagnesium, alloys dzetitanium, kana mamwe maitiro akakosha.

3. Mareferensi Akajairika

  • • GB/T 13913-2008 – Mapurasitiki ekugadzira nickel-phosphorus alloy otomatiki
  • • GB/T 6461-2002 – Kuongororwa kwezviyedzo zvemuenzaniso nezvinhu zvesimbi nezvimwe zvinhu zvisina kugadzirwa pasimbi mushure mekuyedzwa kwengura.
  • • ASTM B733-18 – Tsananguro Yakajairika yeAutocatalytic (Electroless) Nickel-Phosphorus Coatings
  • • ISO 4527:2003 – Kuputira nesimbi – Kuputira nenickel phosphorus alloy otomatiki (isina electron)
  • • GB/T 5270-2005 – Kuputira kwesimbi pamidziyo yesimbi – Kuputira kwakaputirwa nemagetsi uye kwakaiswa mishonga – Nzira dzekuedza kunamira

4. Nheyo yeMaitiro

Kuisa nickel isina electroless inzira yekuisa makemikari otomatiki umo sodium hypophosphite inoderedza maNi²⁺ ions kuti igadzire Ni-P alloy coating.

Maitiro ekuita:

  • • Kusanganiswa kweAnodic: H₂PO₂⁻ + H₂O → H₂PO₃⁻ + 2H⁺ + 2e⁻
  • • Kuderedza Cathodic: Ni²⁺ + 2e⁻ → Ni
  • • Kubatanidzwa kwephosphorus: H₂PO₂⁻ + 2H⁺ + e⁻ → P + 2H₂O

Kupatsanurwa kwezvipfeko zvichienderana nehuwandu hwephosphorus:

Rudzi Kuwanda kwephosphorus
Low-P 1–5%
Pakati-P 5–10%
High-P 10–15%

5. Kuyerera Kwemaitiro

Kuongorora → Kubvisa mafuta → Kusuka kunopisa → Kusuka kunoyerera → Kusvina → Kusuka → Kushanda → Kusuka → Kusuka kweDI → Kuputira pasina electroless → Kupora → Kusuka kwe3-stage counterflow → Passivation → Kusuka kweDI → Kuomesa → Kuongorora → Kurongedza

Nickel isina Electro1
Nickel isina Electro1

6. Magadzirirwo Akakosha Ekuita

Paramita Nzvimbo yekudzora Mashoko
Kuwanda kweNi²⁺ 8–12 g/L Zvinokurudzirwa 9–10 g/L
Sodium hypophosphate 25–35 g/L Chiyero cheMolar kuNi²⁺: 2.5–3.5:1
Mushonga unosanganisa zvinhu (sodium citrate) 30–40 g/L Inosimbisa ma ioni e nickel
Buffer (sodium acetate) 15–25 g/L Inochengetedza pH kugadzikana
kukosha kwepH 4.5–5.5 (Pakati/pamusoro-P) Yakagadziridzwa neammonia kana sodium carbonate
Tembiricha 85–90℃ Yakanakisa 88±1℃
Kurodha 0.5–1.5 dm²/L Kutakura kwakanyanya kunoderedza mwero wekuisa
Mwero wekubvisa mari 15–25 μm/awa Kunoderera nekukwegura kwekugeza
Nguva Maminetsi 15–60 Zvichienderana nehukobvu hunodiwa
Kutsamwa Mhepo yemuchina kana kuti ine simba shoma Kufambisa kana kutenderera kweropa kunokurudzirwa
Kusefa Kusefa kunoenderera mberi, chiyero che5–10 μm Inobvisa zvidimbu, inodzivirira kudonha kwevhu

7. Magadzirirwo eChigadzirwa & Kugona Kupfeka

7.1 Saizi Yebasa

Chinhu Paramita
Saizi yepamusoro 1500×800×600 mm
Saizi diki 5×5×5 mm
Huremu hwakanyanya 200 kg
Huremu hushoma 1 g

7.2 Kugona Kwekuputira Ukobvu

Rudzi Ukobvu hwemhando yepamusoro Kushandiswa kwakajairika
Zvikamu zvemazvo 5–10 μm Threads, vharafu, zvikamu zve hydraulic
Zvikamu zvakajairika 10–50 μm Zvikamu zvinodzivirira ngura nekupfeka
Kuputira gobvu 50–100 μm Kugadzirisa zvipfeko, nzvimbo dzine ngura zvakanyanya

Kufanana: ±10% (zvikamu zvakajairika); ±15% (maumbirwo akaomarara)

7.3 Zvimiro zveKuputira

Pfuma Sekuputirwa Yakarapwa nekupisa (400℃ × 1h) Mashoko
Kuoma (HV) ≥500 HV ≥800 HV Kurapa kupisa kunowedzera kuomarara
Kunamatira ≤ Giredhi 1 (GB/T 5270) Hapana kukwenya, hapana kukwenya
Kuedzwa kwemunyu (NSS, 5% NaCl, 35℃) ≥24 maawa (Pakati-Pakati)
≥72 maawa (High-P)
Pazvinodiwa nevatengi
Kuboorwa kwemvura ≤1 poindi/cm² Kazhinji haina maburi ≥25 μm
Kuramba 50–100 μΩ·cm 30–60 μΩ·cm

Kurapa kupisa: 400℃ ±10℃, awa imwe chete, mhepo/choto chitonhorere.

8. Kugona Kugadzira

Chinhu Kugona
Vhoriyamu yetangi rimwe chete 2–5 m³
Huremu hweboka 500–1500 kg
Kugona kwezuva nezuva matani 3–8
Kugona kwemwedzi wega wega matani 80–200

Cherechedza: Kugona kwega kwega kunoenderana nejometri, ukobvu, uye kukwegura kwebhavhu.

9. Kuongororwa Kwemhando Yepamusoro

9.1 Zvinhu zvekuongorora

Chinhu Maitiro Kakawanda Chinodiwa chekugamuchira
Ukobvu XRF / maikorosikopu yesimbi ≥3 mapoinzi pamutambo wega wega Kudhirowa kwemusangano; kuvandudzwa kwakanyanya ≤10%
Kuoma HV0.1 microhardness Kamwe chete pakuchinjana ≥500 HV (yakafukidzwa); ≥800 HV (HT)
Kunamatira Faira/kukombama/kuchekwa-cheka+tepi Chikamu chimwe chete pabhechi Giredhi ≤1, hapana kukwesha
Chitarisiko Chinoonekwa (chiedza chakajairwa) 100% Yakajeka zvakafanana; hapana zvikanganiso
Munyu wakapfapfaidzwa NSS 5% NaCl, 35℃ Pabhechi/shanduko Pakati-P ≥24 maawa; High-P ≥72 maawa
Kuwanda kwephosphorus EDS / makemikari Vhiki nevhiki / imba yekugezera itsva 1–5% / 5–10% / 10–15%

9.2 Kurongwa kwechitarisiko

Giredhi Tsananguro
Giredhi A Yakafanana yakajeka/yakapenya zvishoma, isina zvikanganiso
Giredhi B Mavanga emvura/epaketi, hapana maburi/maburi ari kudonha
Giredhi C Kusviba kudiki/kusiyana kwemavara, kushanda zvakanaka
Ramba Kukanda, kukwenya, kusvetuka jira, kupisa, musiyano wakakomba wemavara

10. Kugadzirisa matambudziko

Dambudziko Chikonzero chingangoitika Mhinduro
Kusabatana zvakanaka Kubvisa mafuta/kusunga mafuta zvisina kukwana; kusashanda zvakanaka Vandudza kurapwa usati watanga; wedzera kushanda
Kukakavara/kuomarara Zvidimbu zviri mubhavhu; pH yakakwira inokonzeresa Wedzera kusefa (5 μm); pH yakaderera
Kupfeka kusina kujeka/kuchena Ni²⁺/hypophosphate yakaderera; pH/tembiricha yakaderera Wedzera makemikari; pH 4.8–5.2; kupisa kusvika 88℃
Skip plating Kusashanda kwenzvimbo; mafuta/oxide yasara Kuvandudza kushanda; kuderedza mafuta zvakare
Mwero wekuisa zvinhu wakaderera Kupisa kwakaderera/Ni²⁺/kuderedza; pH yakaderera; kugeza kwekare Pisa kusvika 88–90℃; gadzirisa pH; geza nemvura yakachena
Kuora kwebhati Kupisa zvakanyanya; pH yakakwira; kuwedzera nekukurumidza; mutoro wakaderera Mira kupisa; deredza pH; deredza kugeza

11. Kuchengetedzwa

  • • PPE: Magorovhosi ane acid/alkali, magogorosi, apuroni, respirator (ammonia/acids).
  • • Kuchengetera makemikari: Bvisa nickel sulfate, hypophosphite, acids, alkalis; kure nezvinhu zvinoderedza kupisa/kupisa.
  • • Zvinorambidzwa: Musasanganisa conc. acid + hypophosphite (chepfu phosphine). Nyungudutsa zvinhu zvakasimba mumvura yeDI kutanga.
  • • Kufefetera: Utsi hwemunzvimbo yacho huri pamusoro pematangi (kubvisa hydrogen).
  • • Dambudziko: Kugeza maziso, shawa, hupfu hwakaoma/chokudzimisa CO₂, chinhu chinofema, midziyo yekuisira mvura.

12. Kudzivirirwa Kwezvakatipoteredza

  • • Mvura Yakasviba: Mvura yakasviba yakasiyana; pH 9–10 + PAC/PAM; Ni <0.5 mg/L.
  • • Marara ane njodzi: Kugeza kwakashandiswa, mafirita, activator, Ni sludge - kuraswa kwemvumo ne manifest.
  • • Hutsi: Kufefetera nguva dzose; chengetedza ammonia/hydrogen pa GB 16297.
  • • Simba/mvura: Vhara matangi; sukurudza nemvura inoyerera; wedzera mvura yakawanda.

13. Kuumbwa kweBath (Mid‑Phosphorus, Zvikamu Zvakajairika)

Kemikari Kuisa pfungwa pachinhu chimwe chete Basa
NiSO₄·6H₂O 25–35 g/L Munyu mukuru, Ni²⁺ sosi
NaH₂PO₂·H₂O 25–35 g/L Mushonga wekuderedza, P source
Na₃C₆H₅O₇·2H₂O 30–40 g/L Mushonga unoomesa
CH₃COONa·3H₂O 15–25 g/L chivharo chepH
Lactic/propionic acid 5–10 mL/L Chikurumidziso
Chinosimbisa (thiourea) 1–2 mg/L Inodzivirira kuora

Gadzirisa:

1. Nyungudutsa NiSO₄, citrate, acetate mu 1/3 DI mvura, 60℃.

2. Nyungudutsa hypophosphite + lactic acid mune imwe 1/3.

3. Sanganisa, zadza kusvika pahuwandu, pH 4.8–5.2.

4. Wedzera stabilizer, kupisa kusvika 88℃, firita, plate yekuedza.

14. Kugona Kwemidziyo & Kuongorora

14.1 Midziyo mikuru

Midziyo Tsanangudzo
Tangi rekuisa plating PP/PVC yakarongedzwa, yakadziyirwa, uye inodzora tembiricha
Kusefa Pombi inodzivirira asidhi + imba, 5–10 μm, 1–3×/awa
Kudzora tembiricha PID, ±1℃
Ovheni yekuomesa Mhepo inopisa, 60–120℃
Muchina wekuchenesa we ultrasonic 40 kHz, simba rinogadziriswa
Mvura yeDI ≥10 MΩ·cm

14.2 Midziyo yekuongorora

Midziyo Kururama/Standard
Ukobvu hweXRF 0–200 μm, ±0.1 μm
Kuomarara kudiki 10–1000 gf, GB/T 4340.1
Kamuri yekupfapfaidza munyu GB/T 10125, ≥200 L
Maikorosikopu yesimbi 100–1000×, maikoromita
mita yepH ± 0.02, muripo wekupisa
Kuenzanisa kwekuongorora 0.01 g

15. Magwaro & Kutevedza

  • Rekodhi yekugadzira:Nhamba yechikamu, huwandu, tembiricha, pH, nguva, ukobvu, mushandisi.
  • Chirongo chekugezera:Ni²⁺ yezuva nezuva, hypophosphite, pH; kuwedzerwa; kusefa/kuchenesa.
  • Rekodhi yekuongorora:Ukobvu, kuomarara, kunamira, chitarisiko, munyu.
  • Kugadzirisa:Kugadzirisa, kugadzirisa pombi, kubvisa chikero, kutarisa mafeni (kota yega yega).

Kuchengetedza:≥makore matatu (≥makore gumi ekushandisa mota/zvekurapa). Zvinogona kuteverwa nekufamba kwenguva.

16. Zvimwe Zvinodiwa

  • • Inoongororwa gore rega rega neDhipatimendi reTechnical.
  • • Zvinodiwa nevatengi (munyu, kuomarara, kugoverwa, H-embrittlement) zvakanyorwa uye zvinoteverwa.
  • • Zvigadzirwa zvitsva: Kuedza kudiki kutanga; kugadzirwa kwakawanda mushure mekupasa bvunzo dzese.
  • • Yekudzora kugadzirwa uye kuongororwa kwevatengi.

Nhoroondo yeKudzokorora

Mufundisi Zuva Zviri mukati mekugadzirisa Zvatenderwa na
V1.0 2024-xx-xx Kuburitswa kwekutanga
V2.0 2026-04-30 Kugadziridzwa kwakazara kweChirungu chete

 


Nguva yekutumira: Chivabvu-18-2026